Replacing brake pads (not shoes for drum brakes) is a fairly straight forward activity and possibly one of the best (besides perhaps changing engine oil) to perform yourself. Youtube is a great place to start. You can likely even find a full video of pad replacement for your exact model of car.
What is your current knowledge with using basic hand tools such as screwdrivers, hammers, and wrenches (for hex head fasteners)? Do you know how to replace a flat tire? There’s lots of overlap with that procedure and changing brake pads.
If you know not only what a torque wrench is, but how to use it properly you will likely have no trouble changing brake pads.
Full engine rebuilds, or even troubleshooting intermittent CANbus issues, sure. But basic maintenance like brake pads or changing out a failed alternator just require basic hand tools and some minor knowledge you can get from youtube.